The material stuff is a headache in itself, but it's the vacuum created when someone's no longer compis mentis which causes the protracted ordeal of stepping up to take charge. Don't even think of the paperwork coming your way or you'll surely say no!
Not touching this one with a very large stick.
Thank you all for your advice.
My Mother's records were an unorganised mess, it was only that her financial interests were relatively small and simple that allowed me to complete matters in a reasonable time. I took in total probably a month in the UK off work to visit all the companies and officials needed to get everything done including sale of her house and car and sorting out the funeral arrangements etc.
My Father's records - despite his alleged good organisation - were also an utter mess, compounded by him having quite a lot of UK and foreign interests and assets. This time I took probably 6 weeks in the UK off work in total, but the efforts continued from CH for another year to sell his house and another 2 years again until the last item (some US shares held in a US stockbroker) were resolved. Then I had to deal with HMRC over an IHT refund because of overpaid IHT due to house price falls between the date of his death and the date of exchange of sales contracts.
My strong advice: if it's for family and you are the best person in the family to do it then agree to do it, but understand it will take more time and effort and cause more frustration than you would imagine - however in your case since it it's for a friend you should turn it down on the grounds of impracticality.