While I'm sure there are things that will burn "anything" (after all, diesel engines were originally designed on vegetable oil; and the truck I drove during my year in service would happily burn engine oil, diesel, petrol, ethanol, cooking oil or pretty much anything with the word "oil" in the name as long as it was moderately fluid) - I think there's a question of efficiency vs. calorific content of hte fuel, and safety to be considered.
E85 is closer to normal petrol that you think (that's what's in my car right now, as I drove through France); and so are prices. You get a (tax/duties related) discount if buying for your house heating, and I guess you have some advantage to being able to (illegally) fill up your car in an emergency...
That said, I wouldn't go E85 as it's VERY flammable, and the fumes are explosive. Diesel/Heizoel/HVO is relatively difficult to ignite... which is a plus in my book (less chance of an accident happening).
At the end of the day, you need to consider "why do I want this". Is it to hide the fuel pipes? They all have fuel pipes... so unless you go heat pump, that's not a benefit.
Is it for eco-reasons? Then bioethanol is probably best (but honestly I haven't checked); as the byproduct of BURNING is water mainly... but there are massive byproducts in production (it's basically intensive farming + fermentation + distillation).
Is it for self-reliance? In that case, I would look at something that can burn pellets + wood.
You say you have a nearly new boiler - so if I were you... I would keep that, and set aside some money every year. When it breaks, use that pot to replace it with a heat pump or a new boiler.
As much as I like heizoel (it's a 5000l reservoir of diesel in a worst case scenario); I expect that in the next 20-30years, it'll get harder and harder to find as cars move towards electric/hydrogen.
EDIT: Forgot to say, I'm renovating a house in Italy - we're going with gas there. Huge tank buried in the garden, but in a worst case scenario, will run short term from a normal cylinder you can pickup at the petrol station.